Wednesday,September 20
| Osasuna |  | 20.00 |  | Sevilla | ||
| Real Sociedad |  | 20.00 |  | Granada | ||
| Villarreal |  | 22.00 |  | RCD Mallorca | ||
Thursday,September 21
| Atlético Madrid |  | 20.00 |  | Sporting Gijón | ||
| Málaga |  | 20.00 |  | Athletic Bilbao | ||
| Rayo Vallecano |  | 20.00 |  | Levante UD | ||
| Racing Santander |  | 20.00 |  | Real Madrid | ||
| Valencia |  | 22.00 |  | Barcelona | ||
Friday, September 22
| RCD Espanyol |  | 20.00 |  | Getafe | ||
| Real Betis |  | 22.00 |  | Real Zaragoza | ||
Top Score
5 goal - Roberto Soldado (Valencia), Lionel Messi (Barcelona)
4 goal - Cristiano Ronaldo (Real Madrid)
3 goal - Cesc Fábregas (Barcelona), Santi Cazorla (Málaga), IMan.ol Agirretxe (Real Sociedad), Álvaro Negredo (Sevilla FC), Miku (Getafe)
2 goal - Joaquín (Málaga), Xavi (Barcelona), Sergio García (Espanyol), David Villa (Barcelona), Karim Benzema (Real Madrid), Rubén Castro (Real Betis)
